Never posted in the e-sports forums before, but since it's one of the only things we have right now, I'm going to give it a shot.
I think there's definitely $ to be made and even thought there's definitely some volatility, I think there's a lot more data to make educated bets on CSGO of all things than the table tennis and Russian short form hockey that everyone else has been betting up to this point. IMO, those table tennis matches are like flushing your money down the toilet.
So here we go:
Current Record: 0-0
Hard Legion/Espada (No bet)
Two average teams, not a lot to play for. Hard Legion probably wins, but who really knows. No bet.
pro100/Natus Vincere (pro100 +1.5 @ +110)
Natus Vincere has more name recognition, but they've been pretty underwhelming in this tournament, whereas pro100 have been playing better and better together as a team with every match and have a chance to solidify their spot at the top of their group with a win. There have been so many NaVi matches where they just ride S1mple's insane skills to victory, while the rest of the team underachieves. Not a winning strategy to 2-0 a good team like pro100, so the value is here for pro100 to win a map.
Syman/Virtus Pro (Syman +1.5 @ -150)
Syman is a solid and improving young team, whereas VP have struggled to meet expectations and have been losing a lot lately. Good odds on what is essentially a 50/50 match.
fnatic/Complexity (no bet)
I don't see much value here. Complexity likes to play three map matches, but fnatic is way better than them, so could easily 2-0. That said, when is the last time fnatic looked like fnatic? Not touching that ML of -345. Either way, it's a no bet.
Vitality/Ence (over 2.5 maps @-105)
Thinking they split map picks here since neither team is that consistently great and both are subject to lapses in focus. Zywhoo and allu will probably go off on their team's respective map picks and Vitality will win the third map in a close one.
Cloud 9/Envy (over 2.5 maps @-105, 0.5 units on Envy ML @ +115)
Cloud 9 chokes a lot. Envy is really just as good and they have the talent to win at least one map, if not win the match outright.
That's it for now. May update this with bets from the Australian and Asian qualifying rounds for Road to Rio after some research. Australian and Asian CSGO teams are a lot less talented than the European and North/South American teams, so there's more volatility, IMO, but I may find some value.